协鑫纳米 - 钙钛矿技术产业化

2019年3⽉20⽇ 钙钛矿技术产业化 苏州协鑫纳⽶科技有限公司 范斌什么是钙钛矿 CaTiO 3 钛酸钙 BaTiO 3 LaAlO 3 MgSiO 3 NaMgF 3 ABX 3光伏应⽤中的钙钛矿 2019 : (NH 2 CHNH) 0.83 (CH 3 NH 3 ) 0.10 Cs 0.07 Pb(I 0.78 Br 0.22 ) 3 2009 : CH 3 NH 3 PbI 3半导体材料的光电转化能⼒ 1 1.2 1.4 1.6 1.8 1240 1040 890 780 690 nm eV CuInSe 2 (CIS) Si Cu(In,Ga)Se 2 (CIGS) CdTe GaAs GuGaSe 2 a-Si 钙钛矿太阳能电池的转化效率 2000 1995 Efficiency (%) 1990 1985 1980 1975 12 8 4 0 16 20 24 28 32 36 2005 2010 2015 2020 40 44 48 52 Best Research-Cell Efficiencies (Rev. 12-13-2018) Single-Junction GaAs Single crystal Concentrator Thin-film crystal Thin-film crystal Multijunction Cells (2-terminal, monolithic) LM = lattice matched MM = metamorphic IMM = inverted, metamorphic Three-junction (concentrator) Two-junction (concentrator) Three-junction (non-concentrator) Two-junction (non-concentrator) Four-junction or more (concentrator) Four-junction or more (non-concentrator) Crystalline Si Cells Single crystal (concentrator) Multicrystalline Silicon heterostructures (HIT) Single crystal (non-concentrator) Thin-Film Technologies CIGS CdTe Amorphous Si:H (stabilized) CIGS (concentrator) Emerging PV Dye-sensitized cells Organic cells (various types) Perovskite/Si tandem (monolithic) Organic tandem cells Perovskite cells (not stabilized) Inorganic cells (CZTSSe) Qu an t u m d o t ce lls (v ar io u s t y p e s ) NREL (ZnO/PbS-QD) U .Toronto (PbS-QD) MIT U .Toronto U.Toronto NREL Univ. of Queensland 16.6% IBM 12.6% 11.9% EPFL EPFL EPFL EPFL Sharp NIMS Sharp UCLA-Sumitomo UCLA Heliatek Heliatek UCLA Sumi- tomo U. Dresden 11.5% Siemens Groningen U. Linz U. Linz NREL / Konarka U. Linz Plextronics Konarka Mitsubishi HKUST Phillips 66 UCLA Raynergy Tek of Taiwan SCUT-CSU ICCAS Konarka Solarmer 15.6% IBM IBM IBM Oxford PV Oxford PV EPFL Stanford/ASU EPFL KRICT KRICT EPFL KRICT/UNIST KRICT ISCAS ISCAS 23.7% 28.0% UNSW / Eurosolare UNSW Georgia Tech Georgia Tech Georgia Tech Solarex Solarex FhG-ISE Trina FhG-ISE FhG-ISE 22.3% RCA RCA RCA RCA RCA Solarex ARCO UniSolar RCA RCA UniSolar UniSolar (aSi/ncSi/ncSi) AIST AIST LG UniSolar 14.0% Matsushita Monosolar Kodak Kodak Kodak Kodak AMETEK Photon Energy U. So. Florida First Solar First Solar First Solar First Solar GE GE Matsushita NREL NREL 22.1% 22.9% U.of Maine U.of Maine Boeing Boeing Boeing Boeing Boeing ARCO ARCO Boeing Euro-CIS NREL NREL NREL EMPA (Flex poly) NREL NREL NREL ZSW ZSW SolarFron NREL NREL NREL NREL Solibro ZSW SolarFron Solexel Solexel U. Stuttgart U. Stuttgart FhG-ISE ISFH 21.2% Sanyo Sanyo Sanyo Sanyo Sanyo Panasonic Panasonic Panasonic Kaneka Kaneka 26.6% NREL (14x) NREL (15.4x) NREL (14.7x) 23.3% 27.6% SunPower (96x) Stanford (140x) Amonix (92x) UNSW UNSW SunPower (large-area) FhG-ISE ISFH UNSW UNSW UNSW UNSW ARCO RCA Mobil Solar Sandia UNSW UNSW UNSW Spire Stanford Westing- house 26.1% Radboud U. Alta Alta Alta Alta 29.1% Varian (216x) Varian (205x) FhG-ISE (117x) LG NREL (258x) FhG-ISE (232x) 30.5% 27.8% IBM (T.J. Watson Research Center) Kopin Radboud Univ. FhG-ISE LG LG NREL Varian Boeing- Spectrolab (5-J) NREL (6-J) 39.2% 46.0% Soitec (4-J, 319x) FhG-ISE/ Soitec Soitec (4-J, 297x) NREL NREL (4-J, 327x) Alta Alta LG NREL (MM) NREL Varian NREL 32.8% NREL Japan Energy Spire No. Carolina State U. Varian IES-UPM (1026x) NREL (467x) FhG-ISE NREL (38.1x) 35.5% NREL (IMM) Sharp (IMM) Sharp (IMM) Sharp (IMM) Spectrolab 37.9% NREL/ Spectrolab Spectrolab Spectrolab Boeing- Spectrolab Boeing- Spectrolab Boeing- Spectrolab Boeing-Spectrolab (MM, 240x) Boeing-Spectrolab (MM,179x) NREL (IMM) NREL NREL (IMM, 325.7x) FhG-ISE (MM, 454x) SpireSemicon (MM, 406x) SolarJunc (LM, 418x) SolarJunc (LM, 942x) Sharp (IMM, 302x) Spectrolab (MM, 299x) Boeing- Spectrolab (LM, 364x) 44.4% https://ww.nrel.gov/pv/assets/pdf/cell_e!ciency_chart_explanation.pdf (including key to company/lab/organization acronyms & abbreviations)材料的纯度问题 太阳能级硅料纯度：99.9999% 太阳能级钙钛矿材料纯度：99.9999%材料的合成/提纯⼯艺 1100 度以上⾼温 100度以下温度合成材料的吸光能⼒ 180 0.3 每块组件耗硅量：1kg 每块组件消耗钙钛矿：2g实验室级别制备⼯艺⼯艺控制的核⼼涂布和结晶组件化⼯艺真空⼯艺 RPD ，PVD钙钛矿光伏组件的制造成本 3% 9% 14% 5% 37% 32% 达到100MW ⽣产规模之后，钙 钛矿组件的制造成本约为0.94 元/ ⽡，仅相当于单晶硅组件的 50% 。光伏产业的投资价值 /kWh /W 5 4.5 4 3.5 3 2.5 2 0.44 0.39 0.35 0.3 0.26 0.22 0.17 钙钛矿太阳能电池稳定吗？ 钙钛矿是⼀类材料，不是⼀个材料钙钛矿太阳能电池稳定吗？钙钛矿太阳能电池稳定吗？钙钛矿太阳能电池稳定吗？