协鑫纳米 - 钙钛矿技术产业化

2019年3⽉20⽇ 钙钛矿技术产业化 苏州协鑫纳⽶科技有限公司 范斌什么是钙钛矿 CaTiO 3 钛酸钙 BaTiO 3 LaAlO 3 MgSiO 3 NaMgF 3 ABX 3光伏应⽤中的钙钛矿 2019 NH 2 CHNH 0.83 CH 3 NH 3 0.10 Cs 0.07 PbI 0.78 Br 0.22 3 2009 CH 3 NH 3 PbI 3半导体材料的光电转化能⼒ 1 1.2 1.4 1.6 1.8 1240 1040 890 780 690 nm eV CuInSe 2 CIS Si CuIn,GaSe 2 CIGS CdTe GaAs GuGaSe 2 a-Si 钙钛矿太阳能电池的转化效率 2000 1995 Efficiency 1990 1985 1980 1975 12 8 4 0 16 20 24 28 32 36 2005 2010 2015 2020 40 44 48 52 Best Research-Cell Efficiencies Rev. 12-13-2018 Single-Junction GaAs Single crystal Concentrator Thin-film crystal Thin-film crystal Multijunction Cells 2-terminal, monolithic LM lattice matched MM metamorphic IMM inverted, metamorphic Three-junction concentrator Two-junction concentrator Three-junction non-concentrator Two-junction non-concentrator Four-junction or more concentrator Four-junction or more non-concentrator Crystalline Si Cells Single crystal concentrator Multicrystalline Silicon heterostructures HIT Single crystal non-concentrator Thin-Film Technologies CIGS CdTe Amorphous SiH stabilized CIGS concentrator Emerging PV Dye-sensitized cells Organic cells various types Perovskite/Si tandem monolithic Organic tandem cells Perovskite cells not stabilized Inorganic cells CZTSSe Qu an t u m d o t ce lls v ar io u s t y p e s NREL ZnO/PbS-QD U .Toronto PbS-QD MIT U .Toronto U.Toronto NREL Univ. of Queensland 16.6 IBM 12.6 11.9 EPFL EPFL EPFL EPFL Sharp NIMS Sharp UCLA-Sumitomo UCLA Heliatek Heliatek UCLA Sumi- tomo U. Dresden 11.5 Siemens Groningen U. Linz U. Linz NREL / Konarka U. Linz Plextronics Konarka Mitsubishi HKUST Phillips 66 UCLA Raynergy Tek of Taiwan SCUT-CSU ICCAS Konarka Solarmer 15.6 IBM IBM IBM Oxford PV Oxford PV EPFL Stanford/ASU EPFL KRICT KRICT EPFL KRICT/UNIST KRICT ISCAS ISCAS 23.7 28.0 UNSW / Eurosolare UNSW Georgia Tech Georgia Tech Georgia Tech Solarex Solarex FhG-ISE Trina FhG-ISE FhG-ISE 22.3 RCA RCA RCA RCA RCA Solarex ARCO UniSolar RCA RCA UniSolar UniSolar aSi/ncSi/ncSi AIST AIST LG UniSolar 14.0 Matsushita Monosolar Kodak Kodak Kodak Kodak AMETEK Photon Energy U. So. Florida First Solar First Solar First Solar First Solar GE GE Matsushita NREL NREL 22.1 22.9 U.of Maine U.of Maine Boeing Boeing Boeing Boeing Boeing ARCO ARCO Boeing Euro-CIS NREL NREL NREL EMPA Flex poly NREL NREL NREL ZSW ZSW SolarFron NREL NREL NREL NREL Solibro ZSW SolarFron Solexel Solexel U. Stuttgart U. Stuttgart FhG-ISE ISFH 21.2 Sanyo Sanyo Sanyo Sanyo Sanyo Panasonic Panasonic Panasonic Kaneka Kaneka 26.6 NREL 14x NREL 15.4x NREL 14.7x 23.3 27.6 SunPower 96x Stanford 140x Amonix 92x UNSW UNSW SunPower large-area FhG-ISE ISFH UNSW UNSW UNSW UNSW ARCO RCA Mobil Solar Sandia UNSW UNSW UNSW Spire Stanford Westing- house 26.1 Radboud U. Alta Alta Alta Alta 29.1 Varian 216x Varian 205x FhG-ISE 117x LG NREL 258x FhG-ISE 232x 30.5 27.8 IBM T.J. Watson Research Center Kopin Radboud Univ. FhG-ISE LG LG NREL Varian Boeing- Spectrolab 5-J NREL 6-J 39.2 46.0 Soitec 4-J, 319x FhG-ISE/ Soitec Soitec 4-J, 297x NREL NREL 4-J, 327x Alta Alta LG NREL MM NREL Varian NREL 32.8 NREL Japan Energy Spire No. Carolina State U. Varian IES-UPM 1026x NREL 467x FhG-ISE NREL 38.1x 35.5 NREL IMM Sharp IMM Sharp IMM Sharp IMM Spectrolab 37.9 NREL/ Spectrolab Spectrolab Spectrolab Boeing- Spectrolab Boeing- Spectrolab Boeing- Spectrolab Boeing-Spectrolab MM, 240x Boeing-Spectrolab MM,179x NREL IMM NREL NREL IMM, 325.7x FhG-ISE MM, 454x SpireSemicon MM, 406x SolarJunc LM, 418x SolarJunc LM, 942x Sharp IMM, 302x Spectrolab MM, 299x Boeing- Spectrolab LM, 364x 44.4 https//ww.nrel.gov/pv/assets/pdf/cell_eciency_chart_explanation.pdf including key to company/lab/organization acronyms abbreviations材料的纯度问题 太阳能级硅料纯度99.9999 太阳能级钙钛矿材料纯度99.9999材料的合成/提纯⼯艺 1100 度以上⾼温 100度以下温度合成材料的吸光能⼒ 180 0.3 每块组件耗硅量1kg 每块组件消耗钙钛矿2g实验室级别制备⼯艺⼯艺控制的核⼼涂布和结晶组件化⼯艺真空⼯艺 RPD ，PVD钙钛矿光伏组件的制造成本 3 9 14 5 37 32 达到100MW ⽣产规模之后，钙 钛矿组件的制造成本约为0.94 元/ ⽡，仅相当于单晶硅组件的 50 。光伏产业的投资价值 /kWh /W 5 4.5 4 3.5 3 2.5 2 0.44 0.39 0.35 0.3 0.26 0.22 0.17 钙钛矿太阳能电池稳定吗 钙钛矿是⼀类材料，不是⼀个材料钙钛矿太阳能电池稳定吗钙钛矿太阳能电池稳定吗钙钛矿太阳能电池稳定吗